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Highly Diastereoselective Functionalization of Piperidines by Photoredox Catalyzed α-Amino C–H Arylation and Epimerization
We report a photoredox catalyzed α-amino C–H arylation reaction of highly substituted piperidine derivatives with electron deficient cyano(hetero)arenes. The scope and limitations of the reaction were explored, with piperidines bearing multiple substitution patterns providing the arylated products i...
Gardado en:
| Publicado en: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7318553/ https://ncbi.nlm.nih.gov/pubmed/32286827 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b13165 |
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