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Allylic Substitution vs. Suzuki Cross-Coupling: Capitalizing on Chemoselectivity with Bifunctional Substrates
[Image: see text] One catalyst, two reactions; a tale of chemoselectivity: Given the choice between an allylic acetate and a vinylboronate ester, palladium preferentially reacts with the allylic acetate giving the allylic substitution product. In the presence of an aryl bromide and base, Suzuki cros...
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| Главные авторы: | , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2010
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2917587/ https://ncbi.nlm.nih.gov/pubmed/20135655 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200905399 |
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