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Breaking Conjugation: Unusual Regioselectivity with 2-Substituted Allylic Substrates in the Tsuji-Trost Reaction

η(3)-Allyl palladium complexes are key intermediates in Tsuji-Trost allylic substitution reactions. It is well known that (η(3)-1-aryl-3-alkyl substituted allyl)Pd intermediates result in nucleophilic attack at the alkyl substituted terminus. In contrast, the chemistry of (η(3)-1,2,3-trisubstituted...

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Hlavní autoři: Kim, Byeong-Seon, Hussain, Mahmud M., Norrby, Per-Ola, Walsh, Patrick J.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2014
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4045119/
https://ncbi.nlm.nih.gov/pubmed/24910767
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC53035C
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