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Breaking Conjugation: Unusual Regioselectivity with 2-Substituted Allylic Substrates in the Tsuji-Trost Reaction
η(3)-Allyl palladium complexes are key intermediates in Tsuji-Trost allylic substitution reactions. It is well known that (η(3)-1-aryl-3-alkyl substituted allyl)Pd intermediates result in nucleophilic attack at the alkyl substituted terminus. In contrast, the chemistry of (η(3)-1,2,3-trisubstituted...
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| 主要な著者: | , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2014
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4045119/ https://ncbi.nlm.nih.gov/pubmed/24910767 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC53035C |
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