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Stereospecific, Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling of Allylic Pivalates to Deliver Quaternary Stereocenters

Recognizing the importance of all-carbon, quaternary stereocenters in complex molecule synthesis, a stereospecific, nickel-catalyzed cross-coupling of allylic pivalates with arylboroxines to deliver products equipped with quaternary stereocenters and internal alkenes was developed. The enantioenrich...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Cobb, Kelsey M., Rabb-Lynch, Javon M., Hoerrner, Megan E., Manders, Alex, Zhou, Qi, Watson, Mary P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5576553/
https://ncbi.nlm.nih.gov/pubmed/28783357
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b02063
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