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Enantiospecific, Nickel-Catalyzed Cross-Couplings of Allylic Pivalates and Arylboroxines

[Image: see text] We have developed an enantiospecific, nickel-catalyzed cross-coupling of unsymmetric 1,3-disubstituted allylic pivalates with arylboroxines. The success of this reaction relies on the use of BnPPh(2) as a supporting ligand for the nickel(0) catalyst and NaOMe as a base. This method...

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Hlavní autoři: Srinivas, Harathi D., Zhou, Qi, Watson, Mary P.
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2014
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4084837/
https://ncbi.nlm.nih.gov/pubmed/24927013
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol5016724
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