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Nickel-Catalyzed Cross Couplings of Benzylic Pivalates with Arylboroxines: Stereospecific Formation of Diarylalkanes and Triarylmethanes
We have developed a stereospecific, nickel-catalyzed cross coupling of benzylic pivalates with aryl boroxines. The success of this reaction relies on the use of Ni(cod)(2) as catalyst and NaOMe as a uniquely effective base. This reaction has broad scope with respect to the aryl boroxine and benzylic...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4218864/ https://ncbi.nlm.nih.gov/pubmed/23425080 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja312087x |
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