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Chemoselective Reductive Cross-Coupling of 1,5-Diene-3-ols with Alkynes: A Facile Entry to Stereodefined Skipped Trienes

[Image: see text] A convergent synthesis of highly substituted and stereodefined skipped polyenes is described from the reductive cross-coupling of substituted 1,5-diene-3-ols with alkynes. The control of site-selectivity in functionalization of the substituted diene is a central feature of this com...

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Detalhes bibliográficos
Main Authors: Diez, Peter S., Micalizio, Glenn C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2912438/
https://ncbi.nlm.nih.gov/pubmed/20586460
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja103836h
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