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Silylene transfer to α-keto esters and application to the synthesis of γ-lactones
Disubstituted α-hydroxy acids have been synthesized by metal-catalyzed silylene transfer to α-keto esters. A range of substituents are tolerated in the transformation with the exception of branched groups at the vinylic position. The α-hydroxy acid products can be converted into γ-lactones using a v...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2009
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2898151/ https://ncbi.nlm.nih.gov/pubmed/20625460 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2009.05.066 |
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