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Grubbs Cross-Metathesis Pathway for a Scalable Synthesis of γ-Keto-α,β-unsaturated Esters

[Image: see text] A direct and scalable route to γ-keto-α,β-unsaturated esters, useful intermediates in medicinal chemistry and natural products synthesis, is reported. The key step involves the use of Grubbs’ second-generation olefin metathesis catalyst for cross-metathesis of alkyl acrylates and 2...

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Detalhes bibliográficos
Main Authors: Nair, Reji N., Bannister, Thomas D.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3985456/
https://ncbi.nlm.nih.gov/pubmed/24393145
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo4023606
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