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Dynamic Kinetic Resolution of α-Keto Esters via Asymmetric Transfer Hydrogenation
The dynamic kinetic resolution of β-aryl α-keto esters has been accomplished using a newly designed (arene)RuCl(monosulfonamide) transfer hydrogenation catalyst. This dynamic process generates three contiguous stereocenters with remarkable diastereoselectivity through a reduction/lactonization seque...
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| Главные авторы: | , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2012
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3342478/ https://ncbi.nlm.nih.gov/pubmed/22509806 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3027136 |
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