Chargement en cours...
Dynamic Kinetic Asymmetric Cross-Benzoin Additions of β-Stereogenic α-Keto Esters
[Image: see text] The dynamic kinetic resolution of β-halo α-keto esters via an asymmetric cross-benzoin reaction is described. A chiral N-heterocyclic carbene catalyzes the umpolung addition of aldehydes to racemic α-keto esters. The resulting fully substituted β-halo glycolic ester products are ob...
Enregistré dans:
| Auteurs principaux: | , |
|---|---|
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
American Chemical
Society
2014
|
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4210110/ https://ncbi.nlm.nih.gov/pubmed/25299730 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja508521a |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|