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Organometallic mechanism of action and inhibition of the 4Fe-4S isoprenoid biosynthesis protein GcpE (IspG)

We report the results of a series of chemical, EPR, ENDOR, and HYSCORE spectroscopic investigations of the mechanism of action (and inhibition) of GcpE, E-1-hydroxy-2-methyl-but-2-enyl-4-diphosphate (HMBPP) synthase, also known as IspG, an Fe(4)S(4) cluster-containing protein. We find that the epoxi...

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Detalhes bibliográficos
Main Authors: Wang, Weixue, Li, Jikun, Wang, Ke, Huang, Cancan, Zhang, Yong, Oldfield, Eric
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2895101/
https://ncbi.nlm.nih.gov/pubmed/20534554
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1000264107
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