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Experimental and Theoretical EPR Study of Jahn-Teller Active [HIPTN(3)N]MoL Complexes (L = N(2), CO, NH(3))
The trigonally symmetric Mo(III) coordination compounds [HIPTN(3)N]MoL (L = N(2), CO, NH(3); [HIPTN(3)N]Mo = [(3,5-(2,4,6-i-Pr(3)C(6)H(2))(2)C(6)H(3)NCH(2)CH(2))(3)N]Mo) are low-spin d(3), S = 1/2) species that exhibit a doubly-degenerate (2)E ground state susceptible to a Jahn-Teller (JT) distortio...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2891091/ https://ncbi.nlm.nih.gov/pubmed/20429559 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1004619 |
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