EPR Study of the Low-Spin [d(3); S =1/2], Jahn-Teller-Active, Dinitrogen Complex of a Molybdenum Trisamidoamine

[Image: see text] The first EPR study of the trisamidoamine complex, [Mo]N(2), where [Mo] = [Mo(III)[HIPTN(3)N](3-) = [3,5-(2,4,6-i-Pr(3)-C(6)H(2))(2)C(6)H(3)NCH(2)CH(2)](3)N(3-)], reveals that this low-spin (S = ½) [d(3)] complex exhibits a (2)E state that undergoes a pseudo Jahn-Teller distortion...

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Bibliografiske detaljer
Main Authors: McNaughton, Rebecca L., Chin, Jia Min, Weare, Walter W., Schrock, Richard R., Hoffman, Brian M.
Format: Artigo
Sprog:Inglês
Udgivet: 2007
Fag:
Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2597436/
https://ncbi.nlm.nih.gov/pubmed/17341079
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja068546u
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