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EPR Study of the Low-Spin [d(3); S =1/2], Jahn-Teller-Active, Dinitrogen Complex of a Molybdenum Trisamidoamine
[Image: see text] The first EPR study of the trisamidoamine complex, [Mo]N(2), where [Mo] = [Mo(III)[HIPTN(3)N](3-) = [3,5-(2,4,6-i-Pr(3)-C(6)H(2))(2)C(6)H(3)NCH(2)CH(2)](3)N(3-)], reveals that this low-spin (S = ½) [d(3)] complex exhibits a (2)E state that undergoes a pseudo Jahn-Teller distortion...
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| Hauptverfasser: | , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2007
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2597436/ https://ncbi.nlm.nih.gov/pubmed/17341079 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja068546u |
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