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Protonation of the N(2)-reduction catalyst [HIPTN(3)N]Mo(III) investigated by ENDOR spectroscopy
Dinitrogen is reduced to ammonia by the molybdenum complex of L = [HIPTN(3)N](3-) (Mo). The mechanism by which this occurs involves stepwise addition of proton/electron pairs, but how the first pair converts MoN(2) to Mo-N=NH remains uncertain. The first proton of reduction might bind either at N(β)...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3139016/ https://ncbi.nlm.nih.gov/pubmed/21155580 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic102127v |
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