Fe L-edge XAS Determination of Differential Orbital Covalency of Siderophore Model Compounds: Electronic Structure Contributions to High Stability Constants

Most bacteria and fungi produce low-molecular weight iron-chelators called siderophores. Although different siderophore structures have been characterized, the iron binding moieties often contain catecholate or hydroxamate groups. Siderophores function because of their extraordinarily high stability...

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Main Authors: Hocking, Rosalie K., DeBeer George, Serena, Raymond, Kenneth N., Hodgson, Keith O., Hedman, Britt, Solomon, Edward I.
Formato: Artigo
Idioma:Inglês
Publicado: 2010
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2890247/
https://ncbi.nlm.nih.gov/pubmed/20187651
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9090098
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