Fe L- and K-edge XAS of Low-Spin Ferric Corrole: Bonding and Reactivity Relative to Low-Spin Ferric Porphyrin

Corrole is a tetrapyrrolic macrocycle that has one carbon atom less than a porphyrin. The ring contraction reduces the symmetry from D(4h) to C(2v), changes the electronic structure of the heterocycle and leads to a smaller central cavity with three protons rather than the two of a porphyrin. The di...

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Main Authors: Hocking, Rosalie K., DeBeer George, Serena, Gross, Zeev, Walker, F. Ann, Hodgson, Keith O., Hedman, Britt, Solomon, Edward I.
Formato: Artigo
Idioma:Inglês
Publicado: 2009
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2765561/
https://ncbi.nlm.nih.gov/pubmed/19149467
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic802248t
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