Fe L-edge XAS of Low Spin Heme Relative to Non-heme Fe Complexes: Delocalization of Fe d electrons into the Porphyrin Ligand

Hemes (iron porphyrins) are involved in a range of functions in biology including electron transfer, small molecule binding and transport, and O(2) activation. The delocalization of the Fe d-electrons into the porphyrin ring and its effect on the redox chemistry and reactivity of these systems has b...

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Bibliografische gegevens
Hoofdauteurs: Hocking, Rosalie K., Wasinger, Erik C., Yan, Yi-Long, deGroot, Frank M.F., Ann Walker, F., Hodgson, Keith O., Hedman, Britt, Solomon, Edward I.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2007
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Article
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2890250/
https://ncbi.nlm.nih.gov/pubmed/17199290
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja065627h
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