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L-Edge X-ray Absorption Spectroscopic Investigation of {FeNO}(6): Delocalization vs Antiferromagnetic Coupling

NO is a classic non-innocent ligand and iron nitrosyls can have different electronic structure descriptions depending on their spin-state and coordination environment. These highly covalent ligands are found in metalloproteins and are also used as models for Fe-O(2) systems. This study utilizes iron...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Yan, James J., Gonzales, Margarita A., Mascharak, Pradip K., Hedman, Britt, Hodgson, Keith O., Solomon, Edward I.
Format: Artigo
Language:Inglês
Published: 2017
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5322818/
https://ncbi.nlm.nih.gov/pubmed/28006897
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11260
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