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S K-edge XAS as a Probe of Ligand-Metal Bond Covalency: Metal vs Ligand Oxidation in Cu and Ni Dithiolene Complexes
A combination of Cu L-edge and S K-edge X-ray absorption data and density functional theory (DFT) calculations have been correlated with (33)S EPR superhyperfine results to obtain the dipole integral (I(s)) for the S 1s→3p transition for the dithiolene ligand MNT (maleonitriledithiolate) in (TBA)(2)...
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| Autors principals: | , , , , , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2007
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2880206/ https://ncbi.nlm.nih.gov/pubmed/17269767 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0665949 |
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