Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal–ligand interactions

Three [Me(2)NN]Cu(η(2)-L(2)) complexes (Me(2)NN = HC[C(Me)NAr](2); L(2) = PhNO (2), [Image: see text] (3), PhCH[double bond, length as m-dash]CH(2) (4); Ar = 2,6-Me(2)-C(6)H(3); Ar(F) = 3,5-(CF(3))(2)-C(6)H(3)) have been studied by Cu K-edge X-ray absorption spectroscopy, as well as single- and mult...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Tomson, Neil C., Williams, Kamille D., Dai, Xuliang, Sproules, Stephen, DeBeer, Serena, Warren, Timothy H., Wieghardt, Karl
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5647745/
https://ncbi.nlm.nih.gov/pubmed/29308158
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03294b
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