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Au(I)-Catalyzed Cycloisomerizations Terminated by sp(3) C-H Bond Insertion
[Image: see text] The gold(I)-catalyzed cycloisomerization 1,5-enynes and 1,4-allylallenes to tetracyclododecane and tetracyclotridecane derivatives is reported. Complexation of the cationic gold(I) complex to either the alkyne or the allene moiety induces an intramolecular addition of the alkene le...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2880645/ https://ncbi.nlm.nih.gov/pubmed/19206518 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja808780r |
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