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Au(I)-Catalyzed Ring Expanding Cycloisomerizations: Total Synthesis of Ventricosene
[Image: see text] The gold(I)-catalyzed cycloisomerization of enynes containing an embedded cyclopropane unit leads selectively to the formation of ring systems containing the cyclopropylmethyl cation. A subsequent Wagner–Merwein shift provides diastereomerically pure fused cyclobutanes. The utility...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2653418/ https://ncbi.nlm.nih.gov/pubmed/18759435 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol801760w |
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