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Au(I)-Catalyzed Ring Expanding Cycloisomerizations: Total Synthesis of Ventricosene
[Image: see text] The gold(I)-catalyzed cycloisomerization of enynes containing an embedded cyclopropane unit leads selectively to the formation of ring systems containing the cyclopropylmethyl cation. A subsequent Wagner–Merwein shift provides diastereomerically pure fused cyclobutanes. The utility...
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| 主要な著者: | , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2008
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2653418/ https://ncbi.nlm.nih.gov/pubmed/18759435 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol801760w |
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