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Solvation Response Along the Reaction Coordinate in the Active Site of Ketosteroid Isomerase
A light-activated reaction analog has been developed to mimic the catalytic reaction cycle of Δ(5)-3-ketosteroid isomerase in order to probe the functionally relevant protein solvation response to the catalytic charge transfer. Δ(5)-3-ketosteroid isomerase from Pseudomonas putida catalyses a C-H bon...
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| Auteurs principaux: | , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2010
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2871671/ https://ncbi.nlm.nih.gov/pubmed/20397697 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1007849 |
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