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Transition state chirality and role of the vicinal hydroxyl in the ribosomal peptidyl transferase reaction
The ribosomal peptidyl transferase is a biologically essential catalyst responsible for protein synthesis. The reaction is expected to proceed through a transition state approaching tetrahedral geometry with a specific chirality. To establish that stereospecificity, we synthesized two diastereomers...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2008
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2854833/ https://ncbi.nlm.nih.gov/pubmed/18672893 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi800299u |
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