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Ga(III)-Catalyzed Cycloisomerization Approach to (±)-Icetexone and (±)-Epi-Icetexone

[Image: see text] A Ga(III)-catalyzed cycloisomerization reaction provides expedient access to a benzannulated cycloheptadiene bearing a cyano group, which has been applied to the syntheses of several icetexane diterpenoids including icetexone and epi-icetexone. Key to the synthesis is a novel insit...

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Hlavní autoři: de Jesus Cortez, Felipe, Sarpong, Richmond
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2853035/
https://ncbi.nlm.nih.gov/pubmed/20192209
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol902959v
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