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Stereodivergent Metal-Catalyzed Allene Cycloisomerizations
Metal-catalyzed allene cycloisomerizations provide rapid entry into five-membered carbocyclic frameworks, a common motif in natural products and pharmaceuticals. While both Au(I) and Pd(0)-catalyzed allene cycloisomerizations give 5-endo-dig cyclization, Pd prefers the syn diastereomer in contrast t...
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| Pubblicato in: | Synlett |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8249080/ https://ncbi.nlm.nih.gov/pubmed/34219977 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0037-1610746 |
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