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Synthetic studies on the icetexones: enantioselective formal syntheses of icetexone and epi-icetexone

Two strategies for the synthesis of the icetexane diterpenoids icetexone and epi-icetexone that rely on Ga(III)-catalyzed cycloisomerization of alkynyl indene substrates to yield fused [6-7-6] tricycles have been explored. In the first approach, access to a tricycle bearing a gem-dimethyl group pave...

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書誌詳細
主要な著者: de Jesus Cortez, Felipe, Lapointe, David, Hamlin, Amy M., Simmons, Eric M., Sarpong, Richmond
フォーマット: Artigo
言語:Inglês
出版事項: 2013
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3829994/
https://ncbi.nlm.nih.gov/pubmed/24249921
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2013.04.049
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