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Synthetic studies on the icetexones: enantioselective formal syntheses of icetexone and epi-icetexone
Two strategies for the synthesis of the icetexane diterpenoids icetexone and epi-icetexone that rely on Ga(III)-catalyzed cycloisomerization of alkynyl indene substrates to yield fused [6-7-6] tricycles have been explored. In the first approach, access to a tricycle bearing a gem-dimethyl group pave...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3829994/ https://ncbi.nlm.nih.gov/pubmed/24249921 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2013.04.049 |
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