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Ga(III)-Catalyzed Cycloisomerization Approach to (±)-Icetexone and (±)-Epi-Icetexone
[Image: see text] A Ga(III)-catalyzed cycloisomerization reaction provides expedient access to a benzannulated cycloheptadiene bearing a cyano group, which has been applied to the syntheses of several icetexane diterpenoids including icetexone and epi-icetexone. Key to the synthesis is a novel insit...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2853035/ https://ncbi.nlm.nih.gov/pubmed/20192209 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol902959v |
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