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Ga(III)-Catalyzed Cycloisomerization Approach to the Diterpenoid Alkaloids: Construction of a Core Structure for the Hetidines and Hetisines

A versatile core structure has been prepared that should provide a foundation for the syntheses of the hetidine and hetisine type of diterpenoid alkaloids. The synthesis of the caged polycyclic core structure, which features nine contiguous stereocenters, utilizes a Ga(III)-catalyzed cycloisomerizat...

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Detalhes bibliográficos
Main Authors: Hamlin, Amy M., de Jesus Cortez, Felipe, Lapointe, David, Sarpong, Richmond
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3829997/
https://ncbi.nlm.nih.gov/pubmed/23533012
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201209030
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