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Magnesiate Addition/Ring-Expansion Strategy To Access the 6-7-6 Tricyclic Core of Hetisine-Type C(20)-Diterpenoid Alkaloids
A synthetic strategy to access the fused 6–7-6 tricyclic core of hetisine-type C(20)-diterpenoid alkaloids is reported. This strategy employs a Diels-Alder cycloaddition to assemble a fused bicyclic anhydride intermediate, which is elaborated to a vinyl lactone-acetal bearing an aromatic ring in fiv...
Gardado en:
| Publicado en: | Org Lett |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2017
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6287954/ https://ncbi.nlm.nih.gov/pubmed/28820600 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b02260 |
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