A carregar...
Overriding Felkin Control: A General Method for Highly Diastereoselective Chelation-Controlled Additions to α-Silyloxy Aldehydes
According to the Felkin-Anh and Cram-chelation models, nucleophilic additions to α-silyloxy aldehydes procees through a non-chelation pathway due to the steric and electronic properties of the silyl group, giving rise to Felkin addition products. Herein we describe a general method to promote chelat...
Na minha lista:
| Main Authors: | , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2850917/ https://ncbi.nlm.nih.gov/pubmed/20218659 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910717p |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|