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Reactions of Allylmagnesium Reagents with Carbonyl Compounds and Compounds with C=N Double Bonds: Their Diastereoselectivities Generally Cannot Be Analyzed Using the Felkin–Anh and Chelation-Control Models

This review describes the additions of allylmagnesium reagents to carbonyl compounds and to imines, focusing on the differences in reactivity between allylmagnesium halides and other Grignard reagents. In many cases, allylmagnesium reagents either react with low stereoselectivity when other Grignard...

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Détails bibliographiques
Publié dans:Chem Rev
Auteurs principaux: Bartolo, Nicole D., Read, Jacquelyne A., Valentín, Elizabeth M., Woerpel, K. A.
Format: Artigo
Langue:Inglês
Publié: 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7018623/
https://ncbi.nlm.nih.gov/pubmed/31904936
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.chemrev.9b00414
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