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Evidence Against Single-Electron Transfer in the Additions of Most Organomagnesium Reagents to Carbonyl Compounds

A radical clock system was developed to investigate single-electron transfer (SET) in the reactions of organomagnesium reagents with carbonyl compounds. The fluorenylcyclopropyl radical clock was selected because it is the fastest known radical clock. Additions of Grignard reagents to aldehydes or m...

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Bibliografski detalji
Izdano u:J Org Chem
Glavni autori: Bartolo, Nicole D., Woerpel, K. A.
Format: Artigo
Jezik:Inglês
Izdano: 2020
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7337984/
https://ncbi.nlm.nih.gov/pubmed/32407636
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c00481
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