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Pd-Catalyzed Carbonylative Conjugate Addition of Dialkylzinc Reagents to Unsaturated Carbonyls

[Image: see text] The Pd-catalyzed addition of organozinc reagents to unsaturated carbonyls in the presence of carbon monoxide provides 1,4-diketones in good yield. The reaction was studied with a number of substituted cyclic and acyclic ketones as well as α,β-unsaturated aldehydes.

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Autori principali: Custar, Daniel W., Le, Hai, Morken, James P.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2010
Soggetti:
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2929296/
https://ncbi.nlm.nih.gov/pubmed/20687574
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol1013476
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