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Synthesis and Reactivity of Rhodium(II) N-Triflyl Azavinyl Carbenes
[Image: see text] Highly reactive rhodium (II) N-trifluoromethylsulfonyl azavinyl carbenes are formed in situ from NH-1,2,3-triazoles, triflic anhydride, and rhodium carboxylates. They rapidly and selectively react with olefins, providing cyclopropane carboxaldehydes and 2,3-dihydropyrroles in gener...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2834274/ https://ncbi.nlm.nih.gov/pubmed/20131915 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910187s |
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