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Stereoselective 1,3-Insertions of Rhodium(II) Azavinyl Carbenes
Rhodium(II) azavinyl carbenes, conveniently generated from 1-sulfonyl-1,2,3-triazoles, undergo a facile, mild and convergent formal 1,3-insertion into N–H and O–H bonds of primary and secondary amides, various alcohols, and carboxylic acids to afford a wide range of vicinally bis-functionalized Z-ol...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3999524/ https://ncbi.nlm.nih.gov/pubmed/24295389 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja408185c |
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