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Arylation of Rhodium(II) Azavinyl Carbenes with Boronic Acids

A highly efficient and stereoselective arylation of in situ generated azavinyl carbenes affording 2,2-diaryl enamines at ambient temperatures has been developed. These transition metal carbenes are directly produced from readily available and stable 1-sulfonyl-1,2,3-triazoles in the presence of a rh...

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Detalhes bibliográficos
Main Authors: Selander, Nicklas, Worrell, Brady T., Chuprakov, Stepan, Velaparthi, Subash, Fokin, Valery V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3597238/
https://ncbi.nlm.nih.gov/pubmed/22913576
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3062453
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