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Ring Expansion and Rearrangements of Rhodium(II) Azavinyl Carbenes
An efficient, regioselective and convergent method for the ring expansion and rearrangement of 1-sulfonyl-1,2,3-triazoles under rhodium(II)-catalyzed conditions is described. These denitrogenative reactions form substituted enaminone and olefin-based products, which in the former case can be further...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3627540/ https://ncbi.nlm.nih.gov/pubmed/23161725 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201207820 |
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