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Ring Expansion and Rearrangements of Rhodium(II) Azavinyl Carbenes

An efficient, regioselective and convergent method for the ring expansion and rearrangement of 1-sulfonyl-1,2,3-triazoles under rhodium(II)-catalyzed conditions is described. These denitrogenative reactions form substituted enaminone and olefin-based products, which in the former case can be further...

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Detalhes bibliográficos
Main Authors: Selander, Nicklas, Worrell, Brady T., Fokin, Valery V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3627540/
https://ncbi.nlm.nih.gov/pubmed/23161725
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201207820
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