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Synthesis and Reactivity of Rhodium(II) N-Triflyl Azavinyl Carbenes

[Image: see text] Highly reactive rhodium (II) N-trifluoromethylsulfonyl azavinyl carbenes are formed in situ from NH-1,2,3-triazoles, triflic anhydride, and rhodium carboxylates. They rapidly and selectively react with olefins, providing cyclopropane carboxaldehydes and 2,3-dihydropyrroles in gener...

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Bibliografiske detaljer
Main Authors: Grimster, Neil, Zhang, Li, Fokin, Valery V.
Format: Artigo
Sprog:Inglês
Udgivet: 2010
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2834274/
https://ncbi.nlm.nih.gov/pubmed/20131915
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910187s
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