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A New Reaction Motif: “Homo-S(N)2′-Like” Direct Nucleophilic Addition to Neutral η(3)-Allylmolybdenum Complexes. Total Synthesis of the Antimalarial (+)–Isofebrifugine
[Image: see text] Charge neutral TpMo(CO)(2)(5-acyloxy-η(3)-pyranyl) and TpMo(CO)(2)(5-acyloxy-η(3)-pyridinyl) scaffolds undergo a novel intermolecular “homo-S(N)2′-like” reaction with a variety of carbon nucleophiles. Combined with an annulative demetalation, the homo-S(N)2′-like substitution/annul...
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| Hlavní autoři: | , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2009
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2814099/ https://ncbi.nlm.nih.gov/pubmed/19678704 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9056322 |
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