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Novel Substitutions of 1-Alkoxy- and 1-Arylsulfonyloxy-η(3)-Allylmolybdenum Complexes. A Case for η(1)-Alkenyl Carbene Complexes as Intermediates

A series of acyclic and cyclic 1-alkoxy- and 1-arylsulfonyloxy-substituted TpMo(CO)(2)(η(3)-allyl) complexes was synthesized and characterized, and exchange of the oxygenated substituent was investigated under a variety of reaction conditions. 1-Alkoxy-substituted η(3)-allyl and η(3)-butenyl complex...

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Hlavní autoři: Coombs, Thomas C., Huang, Wenwei, Garnier-Amblard, Ethel C., Liebeskind, Lanny S.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2992457/
https://ncbi.nlm.nih.gov/pubmed/21116457
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om100305f
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