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Practical, Scalable, High-Throughput Approaches to η(3)-Pyranyl and η(3)-Pyridinyl Organometallic Enantiomeric Scaffolds Using the Achmatowicz Reaction
A unified strategy for the high throughput synthesis of multigram quantities of the η(3)-oxopyranyl- and η(3)-oxopyridinylmolybdenum complexes TpMo(CO)(2)(η(3)-oxopyranyl) and TpMo(CO)(2)(η(3)-oxopyridinyl) is described (Tp = hydridotrispyrazolylborato). The strategy uses the oxa- and aza-Achmatowic...
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| Main Authors: | , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2652699/ https://ncbi.nlm.nih.gov/pubmed/18171075 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo702006z |
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