Practical, Scalable, High-Throughput Approaches to η(3)-Pyranyl and η(3)-Pyridinyl Organometallic Enantiomeric Scaffolds Using the Achmatowicz Reaction

A unified strategy for the high throughput synthesis of multigram quantities of the η(3)-oxopyranyl- and η(3)-oxopyridinylmolybdenum complexes TpMo(CO)(2)(η(3)-oxopyranyl) and TpMo(CO)(2)(η(3)-oxopyridinyl) is described (Tp = hydridotrispyrazolylborato). The strategy uses the oxa- and aza-Achmatowic...

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Hlavní autoři: Coombs, Thomas C., Lee, Maurice D., Wong, Heilam, Armstrong, Matthew, Cheng, Bo, Chen, Wenyong, Moretto, Alessandro F., Liebeskind, Lanny S.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2008
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2652699/
https://ncbi.nlm.nih.gov/pubmed/18171075
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo702006z
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