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Enantioselective Total Synthesis of (−)-Acutumine
An account of the total synthesis of the tetracyclic alkaloid (−)-acutumine is presented. A first-generation approach to the spirocyclic subunit was unsuccessful due to incorrect regioselectivity in a radical cyclization. However, this work spawned a second-generation strategy in which the spirocycl...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2790369/ https://ncbi.nlm.nih.gov/pubmed/19904909 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo902006q |
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