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Enantioselective Total Synthesis of (−)-Deoxoapodine
The first enantioselective total synthesis of (−)-deoxoapodine is described. Our synthesis of this hexacyclic aspidosperma alkaloid includes an efficient molybdenum-catalyzed enantioselective ring-closing metathesis reaction for desymmetrization of an advanced intermediate that introduces the C5-qua...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5647245/ https://ncbi.nlm.nih.gov/pubmed/28862815 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201708088 |
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